Arai, Kenta; Ueda, Yoshihiro; Morisaki, Kazuhiro; Furuta, Takumi; Sasamori, Takahiro; Tokitoh, Norihiro; Kawabata, Takeo published an article in 2018, the title of the article was Intermolecular chemo- and regioselective aromatic C-H amination of alkoxyarenes promoted by rhodium nitrenoids.Product Details of 321-28-8 And the article contains the following content:
Intermol. aromatic C(sp2)-H amination promoted by neutral rhodium nitrenoids has been developed. The reactions proceeded with various oxygen-substituted arenes ROR1 (R = Me, Et, Bn, etc.; R1 = Ph, 2-fluorophenyl, 2-benzylphenyl, etc.) (1.5 equivalent) in a chemo- and regioselective manner. The aromatic C(sp2)-H amination took place at the para position of the oxygen substituent in the presence of benzylic C(sp3)-H bonds and/or C(sp3)-H bonds α to ethereal oxygen. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Product Details of 321-28-8
The Article related to aryl carbamate preparation chemoselective regioselective, alkoxyarene tosyl trichloroethoxycarbonyl hydroxylamine amination dirhodium catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ureas, Carbamic Acids, Guanidines, and Their Sulfur-Containing Analogs and other aspects.Product Details of 321-28-8
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