On November 17, 2020, Yang, Hai-Long; Li, Zhao-Hui; Liu, Pei-Pei; Sun, Xiao-Wen; Wang, Zhong-Hui; Yao, Hong; Zhang, You-Ming; Wei, Tai-Bao; Lin, Qi published an article.Related Products of 150-78-7 The title of the article was Metal-Free White Light-Emitting Fluorescent Material Based on Simple Pillar[5]arene-tripodal Amide System and Theoretical Insights on Its Assembly and Fluorescent Properties. And the article contained the following:
The booming of host-guest assembly-based supramol. chem. provides abundant ways to construct functional systems and materials. Attracted by the important application prospect of white light emission and aggregation-induced emission (AIE) materials, herein, we report an efficient way for fabricating metal-free white light-emitting AIE materials through the supramol. assembly of simple organic compounds: methoxyl pillar[5]arene (MP5) and tri-(pyridine-4-ylamido)benzene (TAP). By host-guest assembly, MP5 and TAP formed a supramol. polymer (MP5-T); meanwhile, the MP5-T xerogel powder emitted white light at CIE coordinates (0.29 and 0.29). The supramol. assembly and white light-emitting mechanisms were carefully investigated by experiments as well as quantum chem. calculations including d. functional theory (DFT), reduced d. gradient, electrostatic surface potential, independent gradient model, and frontier MO (highest-occupied MO-lowest-unoccupied MO) analyses. Interestingly, according to the experiments and calculations, the supramol. assembly is critical in the white light-emitting phenomenon. Moreover, in this work, the quantum chem. calculations could not only support exptl. phenomena but also provide deep understanding and visualized presentation of the assembly and emission mechanism. In addition, the obtained MP5-T solid powder could serve as a novel and easy means to make material for white light-emitting devices. The experimental process involved the reaction of 1,4-Dimethoxybenzene(cas: 150-78-7).Related Products of 150-78-7
The Article related to metal free white light emitting fluorescence based simple pillar, Optical, Electron, and Mass Spectroscopy and Other Related Properties: Luminescence and other aspects.Related Products of 150-78-7
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem