Thermal and photocatalytic cascade one-pot synthesis of secondary amine using multifunctional Pd decorated MOF-derived CeO2 was written by More, Ganesh Sunil;Kushwaha, Nidhi;Bal, Rajaram;Srivastava, Rajendra. And the article was included in Journal of Colloid and Interface Science in 2022.Related Products of 105-13-5 This article mentions the following:
Pd decorated MOF-derived CeO2 was prepared for the cascade one-pot synthesis of secondary amine by thermal and photocatalytic routes. Among the designed catalysts, Pd(0.5%)/CeO2-300 exhibited the best activity for thermal and photocatalytic one-pot secondary amine synthesis involving benzyl alc. and aniline. The physicochem. characteristics of Pd(0.5%)/CeO2-300 suited for the oxidation of benzyl alc. followed by condensation with aniline to form an imine. Further, reduction of imine over Pd NPs decorated on CeO2-300 took place to form secondary amine. An excellent conversion of benzyl alc. and secondary amine selectivity was observed thermally at 100°C in 26 h. The Pd(0.5%)/CeO2-300 exhibited excellent activity in white LED. Interestingly, more activity was achieved in sunlight. The Pd(0.5%)/CeO2-300 demonstrated excellent stability under thermal and photocatalytic conditions and was recycled 5 times without losing any significant activity. The surface area, acidity, and elemental compositions were characterized by various physicochem. techniques. The light absorption property, bandgap, charge carrier separation, and photocurrent measurements were carried out by photoelectrochem. and optoelectronic anal. The reaction mechanism and structural activity relationship correlated with control experiments, catalytic activity data, physicochem., and optoelectronic characterization. One catalyst affording efficient activity in conventional thermal and photocatalytic conditions, especially sunlight, would be exciting to researchers and industrial practitioners. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Related Products of 105-13-5).
(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Related Products of 105-13-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem