Sundarraman, Balaji et al. published their research in Organometallics in 2022 | CAS: 105-13-5

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Application of 105-13-5

NNO Pincer Ligand-Supported Palladium(II) Complexes: Direct Synthesis of Quinazolines via Acceptorless Double Dehydrogenative Coupling of Alcohols was written by Sundarraman, Balaji;Rengan, Ramesh;Semeril, David. And the article was included in Organometallics in 2022.Application of 105-13-5 This article mentions the following:

A sustainable approach for the synthesis of substituted quinazolines by sequential acceptorless dehydrogenative coupling of 2-aminobenzyl alc. with alcs. using new Pd(II)-NNO pincer-type complexes as catalysts is reported. Air-stable Pd(II) complexes [Pd(L)(PPh3)] (L = 4-substituted Me-2-pyrrolyl benzhydrazone ligands) were synthesized, and their compositions were recognized by anal. and spectral methods (FTIR, NMR, and high-resolution mass spectrometry (HRMS)). Single-crystal x-ray crystallog. confirmed the tridentate coordination of the ligands and the existence of square-planar geometry around the metal ion. A wide range of substituted quinazoline derivatives was synthesized from double dehydrogenation of benzyl alcs. using 1.5 mol % catalyst loading with a maximum of 93% yield. The formation of aminobenzaldehyde and benzaldehyde intermediates via a double dehydrogenative coupling reaction was confirmed by control experiments In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Application of 105-13-5).

(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Application of 105-13-5

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem