H2-Free Selective Dehydroxymethylation of Primary Alcohols over Palladium Nanoparticle Catalysts was written by Yamaguchi, Sho;Kondo, Hiroki;Uesugi, Kohei;Sakoda, Katsumasa;Jitsukawa, Koichiro;Mitsudome, Takato;Mizugaki, Tomoo. And the article was included in ChemCatChem in 2021.Related Products of 111-77-3 This article mentions the following:
In this study, a novel, highly efficient, and reusable heterogeneous catalyst system was established for the H2-free dehydroxymethylation of primary alcs. RCH2OH (R = nonyl, Ph, pyridin-2-yl, oxolan-2-yl, etc.) using cerium oxide-supported palladium nanoparticles (Pd/CeO2). A wide range of aliphatic and aromatic alcs. including biomass-derived alcs. was converted into the corresponding one-carbon shorter hydrocarbons RH in high yields in the absence of any additives, accompanied by the production of H2 and CO. Pd/CeO2 was easily recovered from the reaction mixture and reused, retaining its high activity, thus providing a simple and sustainable methodol. to produce hydrocarbon fuels from biomass-derived oxygenates. In the experiment, the researchers used many compounds, for example, 2-(2-Methoxyethoxy)ethanol (cas: 111-77-3Related Products of 111-77-3).
2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Related Products of 111-77-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem