Enamines. Part V. Synthesis of substituted phenyl benzyl ketones and 2-arylisatogens was written by Kulkarni, Ssheshgiri N.;Kamath, H. V.;Bhamare, N. K.. And the article was included in Indian Journal of Chemistry in 1988.SDS of cas: 5367-32-8 This article mentions the following:
Isatogens I (R1 = H, OMe; R2 = H, OMe, Me) were prepared from nitrodeoxybenzoins II. β-Aminostyrenes were acylated by 2-O2NC6H4COCl, and the products were hydrolyzed to give II. In the experiment, the researchers used many compounds, for example, 3-Methyl-4-nitroanisole (cas: 5367-32-8SDS of cas: 5367-32-8).
3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.SDS of cas: 5367-32-8
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem