Purtsas, Alexander published the artcileIron-Catalyzed Oxidative C-O and C-N Coupling Reactions Using Air as Sole Oxidant, Application In Synthesis of 121-00-6, the main research area is tertiary arylamine phenol hexadecafluorophthalocyanine iron catalyst regioselctive oxidative coupling; diaryl ether preparation; phenothiazine tertiary arylamine hexadecafluorophthalocyanine iron catalyst regioselctive oxidative coupling; phenothiazinyl aryl amine preparation; phenolphenothiazine hexadecafluorophthalocyanine iron catalyst regioselctive oxidative coupling; phenothiazinylphenol preparation; C−H activation; air; homogeneous catalysis; iron; oxidative amination.
The oxygenation of tertiary arylamines, and the amination of tertiary arylamines and phenols was described. The key step of these coupling reactions was an iron-catalyzed oxidative C-O or C-N bond formation which generally provides the corresponding products in high yields and with excellent regioselectivity. The transformations were accomplished using hexadecafluorophthalocyanine-iron(II) (FePcF16) as catalyst in the presence of an acid or a base additive and require only ambient air as sole oxidant.
Chemistry – A European Journal published new progress about Aromatic ethers Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation). 121-00-6 belongs to class ethers-buliding-blocks, name is 4-Hydroxy-3-tert-butylanisole, and the molecular formula is C11H16O2, Application In Synthesis of 121-00-6.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem