Liu, Ying published the artcileEnabling Stable Interphases via In Situ Two-Step Synthetic Bilayer Polymer Electrolyte for Solid-State Lithium Metal Batteries, SDS of cas: 143-24-8, the main research area is bilayer polymer electrolyte interphase solid state lithium metal battery.
Poly(ethylene oxide) (PEO)-based electrolyte is considered to be one of the most promising polymer electrolytes for lithium metal batteries. However, a narrow electrochem. stability window and poor compatibility at electrode-electrolyte interfaces restrict the applications of PEO-based electrolyte. An in situ synthetic double-layer polymer electrolyte (DLPE) with polyacrylonitrile (PAN) layer and PEO layer was designed to achieve a stable interface and application in high-energy-d. batteries. In this special design, the hydroxy group of PEO-SPE can form an O-H—N hydrogen bond with the cyano group in PAN-SPE, which connects the two layers of DLPE at a microscopic chem. level. A special Li+ conducting mechanism in DLPE provides a uniform Li+ flux and fast Li+ conduction, which achieves a stable electrolyte/electrode interface.LiFePO4/DLPE/Li battery shows superior cycling stability, and the coulombic efficiency remains 99.5% at 0.2 C. Meanwhile, LiNi0.6Co0.2Mn0.2O2/DLPE/Li battery shows high specific discharge capacity of 176.0 mAh g-1 at 0.1 C between 2.8 V to 4.3 V, and the coulombic efficiency remains 95% after 100 cycles. This in situ synthetic strategy represents a big step forward in addressing the interface issues and boosting the development of high-energy-d. lithium-metal batteries.
Inorganics published new progress about Battery anodes. 143-24-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11,14-Pentaoxapentadecane, and the molecular formula is C10H22O5, SDS of cas: 143-24-8.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem