Celik Kucuk, Asuman published the artcileFluoride shuttle batteries: On the performance of the BiF3 electrode in organic liquid electrolytes containing a mixture of lithium bis(oxalato)borate and triphenylboroxin, Quality Control of 143-24-8, the main research area is lithium bisoxalato borate triphenylboroxin bismuth trifluoride electrode liquid electrolytes.
In a typical organic liquid electrolyte-based fluoride shuttle battery (FSB), a high concentration of a boron-based anion acceptor (AA) capable of binding specific anions is required to provide a sufficient amount of dissolved fluoride salt. The tetraglyme (G4)-based electrolyte system (LiBOB0.25/TPhBX0.25/sat_CsF/G4) containing equal concentrations of LiBOB, TPhBX, and saturated cesium fluoride (CsF) was prepared The potential effects of reducing the amount of the AA and using a mixture of LiBOB and TPhBX on the electrochem. compatibility of the BiF3 electrode were investigated through cyclic voltammetry, charge-discharge tests, and a.c. impedance measurements. The potential advantages of using the LiBOB/TPhBX mixture as an electrolyte additive include the fact that it increases ionic conductivity, widens the cathodic and anodic stability window, and enhances the electrochem. performance of the BiF3 pos. electrode. Moreover, according to Raman microscopy, the direct insertion mechanism was found to be predominant for the FSB reaction mechanism of BiF3 microparticles in LiBOB0.25/TPhBX0.25/sat_CsF/G4. These improvements can be attributed to the increase in fluorine anion mobility, which occurs when the cesium cation mobility is reduced; this, in turn, is a result of the stabilization of the cesium cation due to the interaction between LiBOB and TPhBX.
Solid State Ionics published new progress about Defluorination. 143-24-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11,14-Pentaoxapentadecane, and the molecular formula is C10H22O5, Quality Control of 143-24-8.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem