Synthesis, structure, and photophysical/chiroptical properties of benzopicene-based π-conjugated molecules was written by Murayama, Koichi;Shibata, Yu;Sugiyama, Haruki;Uekusa, Hidehiro;Tanaka, Ken. And the article was included in Journal of Organic Chemistry in 2017.HPLC of Formula: 16356-02-8 This article mentions the following:
The convenient synthesis of substituted benzopicenes and azabenzopicenes I (X = C, N; R1, R2 = H, CO2Et, alkyl, CH2CH) has been achieved by the cationic rhodium(I)/H8-BINAP or BINAP complex-catalyzed [2+2+2] cycloaddition of 1,1′-dialkynyl-2,2′-binaphthalene under mild conditions. This method was applied to the synthesis of benzopicene-based long ladder (II, R3 = C12H25) and helical (III, R4 = Ph, Bu; Y2 = O, 9-fluorenylidene) mols. The x-ray crystal structure anal. revealed that the benzopicene-based helical mol. is highly distorted and the average distance of overlapped rings is markedly shorter than that in the triphenylene-based helical mol. Photophys. and chiroptical properties of these benzopicene and azabenzopicene derivatives have also been examined With respect to photophys. properties, substituted benzopicenes and azabenzopicenes showed red shifts of absorption and emission maxima compared with the corresponding triphenylenes and azatriphenylenes. With respect to chiroptical properties, the CPL spectra of the benzopicene-based helical mol. showed two opposite peaks, and thus the value of the CPL was smaller than that of the triphenylene-based helical mol. presumably due to the presence of two chiral fluorophores. In the experiment, the researchers used many compounds, for example, 1,4-Dimethoxy-2-butyne (cas: 16356-02-8HPLC of Formula: 16356-02-8).
1,4-Dimethoxy-2-butyne (cas: 16356-02-8) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.HPLC of Formula: 16356-02-8
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem