Ylide methylation of aromatic nitro compounds was written by Traynelis, Vincent J.;McSweeney, John Venard. And the article was included in Journal of Organic Chemistry in 1966.COA of Formula: C8H9NO3 This article mentions the following:
The reaction of dimethyloxosulfonium methylide with nitrobenzene produced ο- and p-nitrotoluenes in about 35% yield with an ortho/para ratio of about 10-15. Addnl. methylation reactions with 1-nitronaphthalene, ο-, m-, and p-chloronitrobenzenes, ο-, m-, and p-nitrotoluene, and m- and p-nitroanisoles are described. Some mechanistic possibilities for the origin of the products are considered. In the experiment, the researchers used many compounds, for example, 3-Methyl-4-nitroanisole (cas: 5367-32-8COA of Formula: C8H9NO3).
3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil. Ethers can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.COA of Formula: C8H9NO3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem