Selective oxidation of primary benzylic alcohols to aldehydes using NaNO3 under ball milling was written by Wang, Jing-Fei;Lu, Li-Yu;Zhang, Pu;Qin, Yu-Jun;Guo, Zhi-Xin. And the article was included in Journal of Chemical Research in 2022.Computed Properties of C8H10O2 This article mentions the following:
A facile method for oxidation of primary benzylic alcs. to the corresponding aldehydes was reported using NaNO3/P2O5 under high-speed ball-milling conditions. This approach was clean, efficient, and exhibits broad functional group compatibility. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Computed Properties of C8H10O2).
(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Computed Properties of C8H10O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem