Photocatalyzed decarboxylation of oxamic acids under near-infrared conditions was written by Ogbu, Ikechukwu Martin;Bassani, Dario M.;Robert, Frederic;Landais, Yannick. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2022.Computed Properties of C5H12O3 This article mentions the following:
Photocatalyzed oxidative decarboxylation of oxamic acids under near-IR irradiation using Os(bptpy)2(PF6)2 as catalyst was reported. The reaction was applied to the synthesis of urethanes RNHC(O)OR1 [R = (CH2)2C6H5, 4-ClC6H4CH2, cyclohexyl, etc.; R1 = Et, i-Pr, CH2CF3, etc.] and heterocyclic amides. Mechanistic studies and comparative penetration depths between the NIR and the visible light mediated processes were discussed. In the experiment, the researchers used many compounds, for example, 2-(2-Methoxyethoxy)ethanol (cas: 111-77-3Computed Properties of C5H12O3).
2-(2-Methoxyethoxy)ethanol (cas: 111-77-3) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Autoxidation is the spontaneous oxidation of a compound in air. In the presence of oxygen, ethers slowly autoxidize to form hydroperoxides and dialkyl peroxides. If concentrated or heated, these peroxides may explode. To prevent such explosions, ethers should be obtained in small quantities, kept in tightly sealed containers, and used promptly.Computed Properties of C5H12O3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem