The electro-oxidation of primary alcohols via a coral-shaped cobalt metal-organic framework modified graphite electrode in neutral media was written by Khakyzadeh, Vahid;Sediqi, Salbin. And the article was included in Scientific Reports in 2022.Formula: C8H10O2 This article mentions the following:
The electro-oxidation of alcs. into corresponding aldehydes achieved enormous attention. However, numerous challenges remain in exploring catalytic systems with high conversion efficiency and selectivity. Considering the worldwide attention toward metal-organic frameworks (MOFs) as outstanding crystalline porous materials, many chemists have been encouraged to use them in organic transformations. In this study, a novel coral-shaped cobalt organic framework was grown onto the surface of a functionalized graphite electrode (Co-MOF/C) to fabricate an efficient modified electrode in the electro-oxidation alcs. The modified Co-MOF/C electrode showed high stability, large surface area, rich pores, and good conductivity as a desirable water-stable working electrode for selective oxidation of alcs. into aldehydes in good to excellent yields under a diffusion-controlled process. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Formula: C8H10O2).
(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. But ether is more polar than alkenes. The unique properties of ethers (i.e., that they are strongly polar, with nonbonding electron pairs but no hydroxyl group) enhance the formation and use of many reagents. For example, Grignard reagents cannot form unless an ether is present to share its lone pair of electrons with the magnesium atom. Complexation of the magnesium atom stabilizes the Grignard reagent and helps to keep it in solution.Formula: C8H10O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem