Lithium-Metal Batteries Using Sustainable Electrolyte Media and Various Cathode Chemistries was written by Marangon, Vittorio;Minnetti, Luca;Adami, Matteo;Barlini, Alberto;Hassoun, Jusef. And the article was included in Energy & Fuels in 2021.HPLC of Formula: 112-49-2 This article mentions the following:
Lithium-metal batteries employing concentrated glyme-based electrolytes and two different cathode chemistries are herein evaluated in view of a safe use of the highly energetic alkali-metal anode. Indeed, diethylene-glycol dimethyl-ether (DEGDME) and triethylene-glycol dimethyl-ether (TREGDME) dissolving lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and lithium nitrate (LiNO3) in concentration approaching the solvents saturation limit are used in lithium batteries employing either a conversion sulfur-tin composite (S:Sn 80:20 weight/weight) or a Li+ (de)insertion LiFePO4 cathode. Cyclic voltammetry (CV) and electrochem. impedance spectroscopy (EIS) clearly show the suitability of the concentrated electrolytes in terms of process reversibility and low interphase resistance, particularly upon a favorable activation. Galvanostatic measurements performed on lithium-sulfur (Li/S) batteries reveal promising capacities at room temperature (25°C) and a value as high as 1300 mAh gS-1 for the cell exploiting the DEGDME-based electrolyte at 35°C. On the other hand, the lithium-LiFePO4 (Li/LFP) cells exhibit satisfactory cycling behavior, in particular when employing an addnl. reduction step at low voltage cutoff (i.e., 1.2 V) during the first discharge to consolidate the solid electrolyte interphase (SEI). This procedure allows a Coulombic efficiency near 100%, a capacity approaching 160 mAh g-1, and relevant retention particularly for the cell using the TREGDME-based electrolyte. Therefore, this work suggests the use of concentrated glyme-based electrolytes, the fine-tuning of the operative conditions, and the careful selection of active materials chem. as significant steps to achieve practical and safe lithium-metal batteries. In the experiment, the researchers used many compounds, for example, 2,5,8,11-Tetraoxadodecane (cas: 112-49-2HPLC of Formula: 112-49-2).
2,5,8,11-Tetraoxadodecane (cas: 112-49-2) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Electron-deficient reagents are also stabilized by ethers. For example, borane (BH3) is a useful reagent for making alcohols. Pure borane exists as its dimer, diborane (B2H6), a toxic gas that is inconvenient and hazardous to use. Borane forms stable complexes with ethers, however, and it is often supplied and used as its liquid complex with tetrahydrofuran (THF).HPLC of Formula: 112-49-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem