Highly (E)-Selective Tri-Substituted Alkene Synthesis by Low-Valent Titanium-Mediated Homolytic Cleavage of Alcohol C-O Bond was written by Suga, Takuya;Takada, Ryusei;Shimazu, Shoma;Sakata, Mizuki;Ukaji, Yutaka. And the article was included in Journal of Organic Chemistry in 2022.Related Products of 105-13-5 This article mentions the following:
Ti-mediated homolytic C-O bond cleavage was useful for cascade radical-ionic reactions. Benzyl alcs. treated with TiCl4(col) (col = 2,4,6-collidine) and Mn powder generated the corresponding benzyl radicals; in addition, their reaction with 2-carboxy-allyl acetates and the subsequent elimination of the acetoxy group yielded α,β-unsaturated carbonyl compounds I [R = Ph, 1-phenylethyl, undecyl, etc.; Ar = Ph, 4-MeOC6H4, 1-naphthyl, etc.] with exclusive (E)-stereoselectivity. The simplicity of the procedure and its wide substrate scope represented a solution to the drawbacks associated with the reactions. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Related Products of 105-13-5).
(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Related Products of 105-13-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem