Accelerated Decomposition of Potassium Permanganate in Ferrocenium Ion as Ferrocenium-Doped Manganese(IV) Oxide for Selective Oxidation of Alcohols was written by Chumkaeo, Peerapong;Poonsawat, Thinnaphat;Yunita, Isti;Temnuch, Natcha;Meechai, Titiya;Kumpan, Nuttapong;Khamthip, Achjana;Chuaitammakit, Laksamee Chaicharoenwimolkul;Chairam, Sanoe;Somsook, Ekasith. And the article was included in Synlett in 2022.Recommanded Product: 105-13-5 This article mentions the following:
Ferrocenium-doped manganese(IV) oxide (Fc+/MnO2) was synthesized through accelerated decomposition of KMnO4 in the presence of ferrocenium ion (Fc+) generated by concentrated sulfuric acid. The corresponding catalysts enabled highly efficient oxidation of alcs. with aldehyde or ketone. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Recommanded Product: 105-13-5).
(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Recommanded Product: 105-13-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem