Rhenium complex-catalyzed deoxygenation and silylation of alcohols with hydrosilane was written by Nishiyama, Yutaka;Xu, Shijie;Hanatani, Yuuki;Tsuda, Susumu;Umeda, Rui. And the article was included in Tetrahedron Letters in 2022.Application of 105-13-5 This article mentions the following:
The reduction of benzylic, tertiary, and allylic alcs. with hydrosilane was efficiently catalyzed by the rhenium complex, such as ReBr(CO)5, to give the corresponding deoxygenarated products, alkanes, in moderate to good yields. In the case of aliphatic secondary alc., the alkane was formed along with the formation of dehydrated products. On the other hand, in the case of primary and cyclic alcs., silylation of alcs. proceeded to form the corresponding silyl ethers. In the experiment, the researchers used many compounds, for example, (4-Methoxyphenyl)methanol (cas: 105-13-5Application of 105-13-5).
(4-Methoxyphenyl)methanol (cas: 105-13-5) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Application of 105-13-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem