Quality Control of Diphenyl oxide. Authors Wang, T; Hoffmann, M; Dreuw, A; Hasagic, E; Hu, C; Stein, PM; Witzel, S; Shi, HW; Yang, YY; Rudolph, M; Stuck, F; Rominger, F; Kerscher, M; Comba, P; Hashmi, ASK in WILEY-V C H VERLAG GMBH published article about in [Wang, Tao; Hu, Chao; Stein, Philipp M.; Witzel, Sina; Shi, Hongwei; Yang, Yangyang; Rudolph, Matthias; Stuck, Fabian; Rominger, Frank; Hashmi, A. Stephen K.] Heidelberg Univ, Organ Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany; [Hoffmann, Marvin; Dreuw, Andreas] Heidelberg Univ, Interdisciplinary Ctr Sci Comp, Neuenheimer Feld 205 A, D-69120 Heidelberg, Germany; [Hasagic, Edina] Sarajevo Univ, Chem Dept, Fac Nat Sci, Zmaja Bosne 33-35, Sarajevo 71000, Bosnia & Herceg; [Kerscher, Marion; Comba, Peter] Heidelberg Univ, Anorgan Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany; [Hashmi, A. Stephen K.] King Abdulaziz Univ KAU, Chem Dept, Fac Sci, Jeddah 21589, Saudi Arabia in 2021.0, Cited 59.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8
The synthesis of aryl amines via the formation of a C-N bond is an essential tool for the preparation of functional materials, active pharmaceutical ingredients and bioactive products. Usually, this chemical connection is only possible by transition metal-catalyzed reactions, photochemistry or electrochemistry. Here, we report a metal-free arene C-H amination using hydroxylamine derivatives under benign conditions. A charge transfer interaction between the aminating reagents TsONHR and the arene substrates enables the chemoselective amination of the arene, even in the presence of various functional groups. Oxygen was crucial for an effective conversion and its accelerating role for the electron transfer step was proven experimentally. In addition, this was rationalized by a theoretical study which indicated the involvement of a dioxygen-bridged complex with a Sandwich-like arrangement of the aromatic starting materials and the aminating agents at the dioxygen molecule.
Quality Control of Diphenyl oxide. Welcome to talk about 101-84-8, If you have any questions, you can contact Wang, T; Hoffmann, M; Dreuw, A; Hasagic, E; Hu, C; Stein, PM; Witzel, S; Shi, HW; Yang, YY; Rudolph, M; Stuck, F; Rominger, F; Kerscher, M; Comba, P; Hashmi, ASK or send Email.
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