An article Exploring Possible Surrogates for Kobayashi’s Aryne Precursors WOS:000513942200041 published article about BENZYNE-CLICK CHEMISTRY; FACILE N-ARYLATION; O-ARYLATION; NUCLEOPHILIC-SUBSTITUTION; SELECTIVE SYNTHESIS; GENERATION; EFFICIENT; PHENOLS; MAGNESIUM; REAGENTS in [Muraca, Ana Carolina A.; Raminelli, Cristiano] Univ Fed Sao Paulo, Inst Ciencias Ambientais Quim & Farmaceut, BR-09972270 Diadema, Brazil in 2020, Cited 107. Product Details of 101-84-8. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8
A class of aryne precursors, that is, 2-(trimethylsilyl)aryl 4-chlorobenzenesulfonates, has been developed through well-established synthetic routes, which allow the formation of arynes under relatively mild conditions. All the aryne precursors were obtained from phenols and 4-chlorobenzenesulfonyl chloride, an inexpensive and easy-to-handle reagent with relatively low toxicity, and subjected to nucleophilic addition reactions, providing addition products in yields of 24 to 92%, and to cycloaddition reactions, affording cycloadducts in yields up to 80%. This work provides interesting insights into the mechanisms of aryne generation. In addition, 2-(trimethylsilyl)phenyl 4-chlorobenzenesulfonate was successfully employed in the total synthesis of (+/-)-aporphine.
About Diphenyl oxide, If you have any questions, you can contact Muraca, ACA; Raminelli, C or concate me.. Product Details of 101-84-8
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem