Computed Properties of C14H14O. Wu, XY; Qiao, K; Qin, H; Zhang, D; Gao, D; Yang, Z; Fang, Z; Guo, K in [Wu, Xiaoyu; Qiao, Kai; Qin, Hong; Zhang, Dong; Gao, Di; Fang, Zheng; Guo, Kai] Nanjing Tech Univ, Coll Biotechnol & Pharmaceut Engn, Nanjing 211816, Jiangsu, Peoples R China; [Yang, Zhao] China Pharmaceut Univ, Sch Engn, 639 Longmian Ave, Nanjing 211198, Jiangsu, Peoples R China; [Fang, Zheng; Guo, Kai] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China published Silver(i)-mediated oxidative C(sp(3))-H amination of ethers with azole derivatives under mild conditions in 2019, Cited 68. The Name is Benzyl ether. Through research, I have a further understanding and discovery of 103-50-4.
A silver(i)-mediated oxidative N-H/C(sp(3))-H coupling of NH-azoles with ethers has been developed. Various substrates were well N-alkylated in this methodology and the corresponding desired products were given in moderate to good yields. Moreover, the late-stage alkylation of bioactive molecules was achieved. This protocol involved C(sp(3))-N bond formation via a radical pathway generated in the presence of low cost and readily available heptafluoroisopropyl iodide (i-C3F7I). Generally, this reaction features excellent functional group compatibility, broad substrate scope, good regioselectivity, and fast access to pharmaceuticals such as SQ 22536.
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem