Product Details of 101-84-8. I found the field of Materials Science very interesting. Saw the article Facet-dependent Catalysis of CuNi Nanocatalysts toward 4-Nitrophenol Reduction Reaction published in 2020.0, Reprint Addresses Fang, JY (corresponding author), SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA.; Fang, JY (corresponding author), SUNY Binghamton, Mat Sci & Engn Program, Binghamton, NY 13902 USA.. The CAS is 101-84-8. Through research, I have a further understanding and discovery of Diphenyl oxide.
We report a facile method to fabricate CuNi nano-octahedra and nanocubes using a colloidal synthesis approach. The CuNi nanocrystals terminated with exclusive crystallographic facets were controlled and achieved by a group of synergetic capping ligands in a hot solution system. Specifically, the growth of {111}-bounded CuNi nano-octahedra is derived by a thermodynamic control, whereas the generation of {100}-terminated CuNi nanocubes is steered by a kinetic capping of chloride. Using a reduction of 4-nitrophenol with sodium borohydride as a model reaction, CuNi nano-octahedra and nanocubes demonstrated a strong facet-dependence due to their different surface energies although both exhibited remarkable catalytic activity with the high rate constant over mass (k/m). A kinetic study indicated that this is a pseudo first-order reaction with an excess of sodium borohydride. CuNi nanocubes as the catalysts showed better catalytic performance (k/m = 385 s(-1)center dot g(-1)) than the CuNi nano-octahedra (k/m = 120 s(-1)center dot g(-1)), indicating that 4-nitrophenol and hydrogen were adsorbed on the {100} facets with their molecules parallel to the surface much easier than those on {111} facets.
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