I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Phenylglyoxylic Acid: An Efficient Initiator for the Photochemical Hydrogen Atom Transfer C-H Functionalization of Heterocycles published in 2020. Safety of Benzyl ether, Reprint Addresses Kokotos, CG (corresponding author), Natl & Kapodistrian Univ Athens, Dept Chem, Lab Organ Chem, Athens 15771, Greece.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether
C-H functionalization at the alpha-position of heterocycles has become a rapidly growing area of research. Herein, a cheap and efficient photochemical method was developed for the C-H functionalization of heterocycles. Phenylglyoxylic acid (PhCOCOOH) could behave as an alternative to metal-based catalysts and organic dyes and provided a very general and wide array of photochemical C-H alkylation, alkenylation, and alkynylation, as well as C-N bond forming reaction methodologies. This novel, mild, and metal-free protocol was successfully employed in the functionalization of a wide range of C-H bonds, utilizing not only O- or N-heterocycles, but also the less studied S-heterocycles.
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem