An article Generation of Carbocations under Photoredox Catalysis: Electrophilic Aromatic Substitution with 1-Fluoroalkylbenzyl Bromides WOS:000589942900092 published article about SUPERCRITICAL CARBON-DIOXIDE; PHARMACOPHORE; DERIVATIVES in [Kuang, Cuiwen; Zhou, Xin; Xie, Qiqiang; Ni, Chuanfa; Hu, Jinbo] Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China; [Gu, Yucheng] Syngenta, Jealotts Hill Int Res Ctr, Bracknell RG42 6EY, Berks, England in 2020.0, Cited 42.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8. Formula: C12H10O
A novel Friedel-Crafts-type alkylation of arenes to access valuable 1-fluoroalkyl-1,1-biaryl compounds is established under mild conditions. The key to success is the efficient generation of a destabilized benzylic carbocation intermediate via two consecutive single-electron transfer processes by virtue of visible-light photoredox catalysis. This unique activation pattern avoids using strong Lewis acids and high temperatures that are required for generation of destabilized carbocations in traditional Friedel-Crafts reactions. This protocol demonstrates the first example of photoredox-catalyzed heterolysis of electronically deactivated benzylic C-Br bonds for the formation of destabilized carbocation intermediates.
Welcome to talk about 101-84-8, If you have any questions, you can contact Kuang, CW; Zhou, X; Xie, QQ; Ni, CF; Gu, YC; Hu, JB or send Email.. Formula: C12H10O
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem