Xia, Aiyou; Lv, Peizhuo; Xie, Xin; Liu, Yuanhong published the artcile< Nickel-Catalyzed Cyanation of Unactivated Alkyl Sulfonates with Zn(CN)2>, HPLC of Formula: 52244-70-9, the main research area is nickel catalyst cyanation unactivated alkyl sulfonate zinc cyanide; alkyl nitrile preparation.
Cyanation of unactivated primary and secondary alkyl mesylates with Zn(CN)2 catalyzed by nickel has been developed. The reaction provides an efficient route for the synthesis of alkyl nitriles with wide substrate scope, good functional group tolerance, and compatibility with heterocyclic compounds Mechanistic studies indicate that alkyl iodide generated in situ serves as the reactive intermediate and the gradual release of alkyl iodide is crucial for the success of the reaction.
Organic Letters published new progress about Alkanesulfonates Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, HPLC of Formula: 52244-70-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem