The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 1163-19-5, Name is 6,6′-Oxybis(1,2,3,4,5-pentabromobenzene), SMILES is BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC2=C(Br)C(Br)=C(Br)C(Br)=C2Br, in an article , author is Zhuang, Bi-Yang, once mentioned of 1163-19-5, Product Details of 1163-19-5.
Radical-Hydroboration-Involved One-Pot Synthesis of Boron-Handled Glycol Derivatives
A one-pot two-step protocol for the direct synthesis of boron-handled glycol derivatives is reported. The procedure starts by an NHC-boryl-radical-promoted regioselective hydroboration of glycol-protected cinnamaldehydes. After that, the reaction mixture is treated with pinacol in the presence of HCl, leading to the direct formation of pinacol boronate handled glycol monoalkyl ethers. In this acid-triggered conversion, a reductive ring-opening of glycol-derived acetal moiety takes place, during which an NHC-borane unit serves as the hydride source.
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