Quality Control of Diphenyl oxide. Dimakos, V; Su, HY; Garrett, GE; Taylor, MS in [Dimakos, Victoria; Su, Hsin Y.; Garrett, Graham E.; Taylor, Mark S.] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada published Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis in 2019.0, Cited 53.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.
Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by C-C bond formation with net retention of configuration, are obtained. Computational modeling supports a mechanism involving formation of a tetracoordinate borinic ester, which accelerates hydrogen atom transfer with the quinuclidine-derived radical cation through polarity-matching and/or ion-pairing effects.
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Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem