Recommanded Product: Diphenyl oxide. In 2020 POLYHEDRON published article about N-HETEROCYCLIC CARBENE; COX-2 SELECTIVE INHIBITORS; COUPLING REACTIONS; NANO-PARTICLES; DIARYL ETHERS; ARYL HALIDES; REDUCTIVE ELIMINATION; DIRECT C5-ARYLATION; EFFICIENT CATALYST; IMIDAZOLES in [Bhatt, Ramprasad] Birla Inst Technol & Sci, Dept Chem, Pilani Campus, Pilani 333031, Rajasthan, India; [Sharma, Alpesh K.] Indian Inst Technol Delhi, Dept Chem, New Delhi 110016, India; [Himanshi; Joshi, Hemant] Cent Univ Rajasthan, Sch Chem Sci & Pharm, Dept Chem, ISC Lab, NH 8, Ajmer 305817, Rajasthan, India; [Bhuvanesh, Nattamai] Texas A&M Univ, Dept Chem, POB 30012, College Stn, TX 77842 USA in 2020, Cited 73. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.
This report describes the syntheses of N,E (E = S, Se) coordinated bidentate palladium complexes, by the reaction of N-(2-bromobenzyl)-2-(phenylthio/selanyl)ethanamine (3, 4) with [PdCl2(CH3CN)(2)]. The new ligands and palladium complexes were characterized by techniques like H-1, C-13{H-1} NMR, IR, and elemental analysis. The coordination modes of ligand with palladium precursor in complexes 5 and 6 were authenticated by single crystal X-ray diffraction. The complexes possess distorted square planar geometry around palladium center. Thermally robust and air stable complexes 5 and 6 were used as catalyst for regioselective arylation of imidazole and O-arylation of phenol. In case of regioselective arylation of imidazole, the reaction proceeds smoothly under mild reaction conditions, only 2.0 mol% of catalyst loading is required to achieve high yield (76-92%). This protocol is applicable to a broad substrate scope showing excellent tolerance towards different functional groups. Whereas for O-arylation of phenol also only 2.0 mol% catalyst loading is sufficient to give good yield (71-92%) with excellent tolerance towards a broad range of functional groups. Among sulfur and selenium coordinated ligands, selenium ligand coordinated complex, was found to outperform the catalytic reactions in both cases as compare to sulfur ligand. The mercury and triphenylphosphine poisoning tests suggest homogeneous nature of catalysis. (C) 2020 Elsevier Ltd. All rights reserved.
Recommanded Product: Diphenyl oxide. Bye, fridends, I hope you can learn more about C12H10O, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem