Safety of Diphenyl oxide. Mapukata, S; Nwahara, N; Nyokong, T in [Mapukata, Sivuyisiwe; Nwahara, Nnamdi; Nyokong, Tebello] Rhodes Univ, Inst Nanotechnol Innovat, Dept Chem, ZA-6140 Makhanda, South Africa published The photodynamic antimicrobial chemotherapy of Stapphylococcus aureus using an asymmetrical zinc phthalocyanine conjugated to silver and iron oxide based nanoparticles in 2020.0, Cited 46.0. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8.
The synthesis and characterisation of asymmetrical zinc(II) 2(3)-mono-isophthalic acid-9(10),16(17),23 (24)-tri (tert-butylphenoxy) phthalocyanine (complex 4) are reported. The phthalocyanine is conjugated to cysteamine capped silver nanoparticles (Cys-Ag NPs), amine functionalised iron oxide magnetic nanoparticles (NH2-Fe3O4 NPs) and a core-shell composite of the two (Cys-Fe3O4@Ag) via amide bonds. The photo-physico-chemical properties of complex 4 and its respective nanoconjugates (4-Ag, 4-Fe3O4 NPs and 4-Fe3O4@Ag NPs) are also reported. The nanoconjugates showed improved triplet and singlet oxygen quantum yields compared to complex 4. The antibacterial activity of complex 4 and its nanoconjugates were also evaluated on S. aureus wherein their activity was found to be mainly visible light driven with the best catalyst being 4-Fe3O4@Ag. The work therefore demonstrates the feasibility of phthalocyanine-nanoparticle based compounds as potential agents in real life antibacterial treatment.
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