Name: Benzyl ether. I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article DMSO-Triggered Complete Oxygen Transfer Leading to Accelerated Aqueous Hydrolysis of Organohalides under Mild Conditions published in 2019, Reprint Addresses Liu, JP; Xu, Q (corresponding author), Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China.; Xu, Q (corresponding author), Yangzhou Univ, Inst Pesticide, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China.; Xu, Q (corresponding author), Yangzhou Univ, Sch Hort & Plant Protect, Yangzhou 225002, Jiangsu, Peoples R China.. The CAS is 103-50-4. Through research, I have a further understanding and discovery of Benzyl ether.
Addition of DMSO is found to greatly accelerate the aqueous hydrolysis of organohalides to alcohols, providing a neutral, more efficient, milder and more economic process. Mechanistic studies using O-18-DMSO and O-18-H2O showed that, contrary to the opinion that DMSO works as a dipolar solvent to enhance water’s nucleophilicity, the accelerating effect comes from a complete oxygen transfer from DMSO to organohalides through generation of ROS+Me2.X- salts through C-O bond formation, followed by O-S bond disassociative hydrolysis of ROS+Me2.X- with water. This method is applicable to a wide range of organohalides and thus may have potential for practical industrial application, owing to easy recovery of DMSO from the H2O/DMSO mixture by regular vacuum rectification.
Welcome to talk about 103-50-4, If you have any questions, you can contact Liu, HC; Liu, JP; Cheng, XK; Jia, XJ; Yu, L; Xu, Q or send Email.. Name: Benzyl ether
Reference:
Ether – Wikipedia,
,Ether | (C2H5)2O – PubChem