An article Palladium-Borane Cooperation: Evidence for an Anionic Pathway and Its Application to Catalytic Hydro-/Deutero-dechlorination WOS:000494501500001 published article about TRANSITION-METAL-COMPLEXES; Z-TYPE LIGANDS; LEWIS-ACIDS; BOND-ACTIVATION; H ACTIVATION; BORON; H-2; COORDINATION; NICKEL; HYDROSILYLATION in [Kameo, Hajime; Yamamoto, Jun; Asada, Ayaka; Matsuzaka, Hiroyuki] Osaka Prefecture Univ, Grad Sch Sci, Dept Chem, Naka Ku, Gakuen Cho, Sakai, Osaka 5998531, Japan; [Nakazawa, Hiroshi] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan; [Bourissou, Didier] Univ Paul Sabatier, CNRS UMR 5069, Lab Heterochim Fondamentale & Appl, 118 Route Narbonne, F-31062 Toulouse 09, France in 2019, Cited 64. Application In Synthesis of Diphenyl oxide. The Name is Diphenyl oxide. Through research, I have a further understanding and discovery of 101-84-8
Metal-Lewis acid cooperation provides new opportunities in catalysis. In this work, we report a new type of palladium-borane cooperation involving anionic Pd-0 species. The air-stable DPB palladium complex 1 (DPB=diphosphine-borane) was prepared and reacted with KH to give the Pd-0 borohydride 2, the first monomeric anionic Pd-0 species to be structurally characterized. The boron moiety acts as an acceptor towards Pd in 1 via Pd -> B interaction, but as a donor in 2 thanks to B-H-Pd bridging. This enables the activation of C-Cl bonds and the system is amenable to catalysis, as demonstrated by the hydro-/deutero-dehalogenation of a variety of (hetero)aryl chlorides (20 examples, average yield 85 %).
Welcome to talk about 101-84-8, If you have any questions, you can contact Kameo, H; Yamamoto, J; Asada, A; Nakazawa, H; Matsuzaka, H; Bourissou, D or send Email.. Application In Synthesis of Diphenyl oxide
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