Kende, Andrew S.; Curran, Dennis P. published the artcile< Total synthesis of juncusol>, Application In Synthesis of 56724-03-9, the main research area is juncusol total synthesis; cyclization vinylhydroxymethylbiphenyl photochem; biphenyl vinyl hydroxymethyl photocyclization.
Juncusol (I) was prepared from 2,3-Me(MeO)C6H3CHO in 12 steps through coupling of bromide II (R = Br) with iodide II (R = iodo) to give diimine III (R = R1 = (cyclohexylimino)methyl]. The ring skeleton in I was constructed by conversion of the diimine to III (R = CH:CH2, R1 = CH2OH) followed by photocyclization.
Tetrahedron Letters published new progress about Photocyclization. 56724-03-9 belongs to class ethers-buliding-blocks, and the molecular formula is C9H10O2, Application In Synthesis of 56724-03-9.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem