SDS of cas: 33100-27-5In 2020 ,《Transforming Porous Organic Cages into Porous Ionic Liquids via a Supramolecular Complexation Strategy》 appeared in Angewandte Chemie, International Edition. The author of the article were Jie, Kecheng; Onishi, Nicole; Schott, Jennifer A.; Popovs, Ilja; Jiang, De-en; Mahurin, Shannon; Dai, Sheng. The article conveys some information:
Porous liquids are a type of porous materials that engineer permanent porosity into unique flowing liquids, exhibiting promising functionalities for a variety of applications. Here a Type I porous liquid is synthesized by transforming porous organic cages into porous ionic liquids via a supramol. complexation strategy. Simple phys. mixing of 18-crown-6 with task-specific anionic porous organic cages affords a porous ionic liquid with anionic porous organic cages as the anionic parts and 18-crown-6/potassium ion complexes as the cationic parts. In contrast, mixing of 15-crown-5 and anionic porous organic cages in a 2:1 ratio gives only solids, while the addition of excess 15-crown-5 affords a Type II porous liquid The permanent porosity in the cage-based porous liquids has been also confirmed by mol. simulation, positron (e+) annihilation lifetime spectroscopy, and enhanced gas sorption capacity compared with pure crown ethers. In the experimental materials used by the author, we found 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5SDS of cas: 33100-27-5)
1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. SDS of cas: 33100-27-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem