Sagane, Fumihiro; Ogi, Kenta; Konno, Akinori; Kanamura, Kiyoshi published an article in 2021. The article was titled 《The effect of the coordination ability on the Mg plating/stripping behavior in Mg(N(CF3SO2)2)2/glyme based electrolytes》, and you may find the article in Journal of the Electrochemical Society.Application of 33100-27-5 The information in the text is summarized as follows:
The effect of the coordination ability of the solvent species on the Mg plating/stripping behavior was investigated. The Mg plating reaction in Mg(N(CF3SO2)2)2/diglyme was inhibited by the equimolar of 15-crown-5 ether (15C5) to Mg2+-ion. On the other hand, Mg plating took place in the solution by reducing the amount of 15C5 less than that of Mg2+-ion. FT-IR spectra showed that 15C5 preferentially solvated Mg2+-ion in the glyme based solutions The theor. calculation indicated the interaction between Mg2+-ion and each O atom in 15C5 was stronger than that with diglyme or larger sized crown ether. The results showed that the coordination ability of the solvent species could be the critical for the Mg plating reaction. The experimental process involved the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Application of 33100-27-5)
1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Application of 33100-27-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem