Xiong, Ni; Li, Yang; Zeng, Rong published the artcile< Iron-Catalyzed Photoinduced Remote C(sp3)-H Amination of Free Alcohols>, Safety of 4-(4-Methoxyphenyl)-1-butanol, the main research area is alkanol diazene iron catalyst regioselective photoredox amination; aminoalkanol preparation.
A general photocatalytic protocol for the remote C(sp3)-H bond amination of free alkanols was reported. The electron transfer between the abundant and inexpensive catalyst FeCl3 and simple alkanols under blue LED irradiation enabled the alkoxy radical formation under mild redox-neutral conditions, without addnl. oxidant and prefunctionalization. The subsequent selective 1,5-hydrogen atom transfer (HAT) and amination provided a simple and efficient way to access mol. complexity from readily available and bulk alcs.
Organic Letters published new progress about Aliphatic alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 52244-70-9 belongs to class ethers-buliding-blocks, and the molecular formula is C11H16O2, Safety of 4-(4-Methoxyphenyl)-1-butanol.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem