Li, Wu; Qu, Ruiyang; Liu, Weiping; Bourriquen, Florian; Bartling, Stephan; Rockstroh, Nils; Junge, Kathrin; Beller, Matthias published their research in Chemical Science in 2021. The article was titled 《Copper-catalysed low-temperature water-gas shift reaction for selective deuteration of aryl halides》.Product Details of 2398-37-0 The article contains the following contents:
Herein, a practical and stable heterogeneous copper catalyst permits for dehalogenative deuteration via water-gas shift reaction at comparably low temperature This novel approach allows deuteration of diverse (hetero)aryl halides RBr (R = 6-methoxynaphthalen-2-yl, 3-cyano-4-(morpholin-4-yl)phenyl, 2-phenylpyridine, etc.) with good functional group tolerance, and no reduction of the aromatic rings or other easily reducible formyl and cyano groups. Multi-gram experiments show the potential of this method in organic synthesis and medicinal chem. In the experiment, the researchers used many compounds, for example, 1-Bromo-3-methoxybenzene(cas: 2398-37-0Product Details of 2398-37-0)
1-Bromo-3-methoxybenzene(cas: 2398-37-0) is a compound useful in organic synthesis and other chemical processes. It is an intermediate used for pharmaceuticals, perfumes and agrochemicals.Product Details of 2398-37-0
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