In 2019,ACS Catalysis included an article by Zhu, Jiancheng; Lindsay, Vincent N. G.. Application In Synthesis of 1-Bromo-3-methoxybenzene. The article was titled 《Benzimidazolyl Palladium Complexes as Highly Active and General Bifunctional Catalysts in Sustainable Cross-Coupling Reactions》. The information in the text is summarized as follows:
A mononuclear and three dinuclear benzimidazolylpalladium complexes such as I·2 PF6- were prepared I·2 PF6- was an air- and moisture-stable catalyst for Suzuki, Sonogashira, and Heck coupling reactions using 0.1-1 mol% catalyst. Changes in the tether between the 2-benzimidazolyl moiety and the pyridine moiety altered the rigidity and conformation of the ligand scaffold and significantly changed the catalytic activities of the complexes. The structures of the mononuclear palladium complex and of two dinuclear benzimidazolylpalladium complexes, including I·2 PF6-·3 MeCN, were determined by X-ray crystallog. The experimental part of the paper was very detailed, including the reaction process of 1-Bromo-3-methoxybenzene(cas: 2398-37-0Application In Synthesis of 1-Bromo-3-methoxybenzene)
1-Bromo-3-methoxybenzene(cas: 2398-37-0) is a compound useful in organic synthesis and other chemical processes. It is an intermediate used for pharmaceuticals, perfumes and agrochemicals.Application In Synthesis of 1-Bromo-3-methoxybenzene
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