Font, Marc; Spencer, Andrew R. A.; Larrosa, Igor published an article in 2018, the title of the article was meta-C-H arylation of fluoroarenes via traceless directing group relay strategy.Product Details of 321-28-8 And the article contains the following content:
While several methods for the ortho selective arylation of fluoroarenes, meta-functionalization has never been achieved. We report a new methodol., based on the traceless directing group relay concept, leading to the first meta-selective (hetero)arylation of fluoroarenes. In this strategy, CO2 is introduced as a transient directing group, to control a Pd-catalyzed arylation meta to the fluoro functionality, prior to its release in a sequential, one-pot fashion. This method has shown compatibility with a number of functional groups and substitution patterns in both the fluoroarene core and aryl iodide coupling partners, and proceeds with complete meta-selectivity and mono vs. bis-arylation selectivity. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Product Details of 321-28-8
The Article related to fluoro biaryl preparation regioselective, aryl fluoride aryl iodide arylation decarboxylation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Halides and Halonium Compounds and other aspects.Product Details of 321-28-8
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