On July 16, 2021, Kolb, Simon; Ahlburg, Nils L.; Werz, Daniel B. published an article.Formula: C8H10O2 The title of the article was Friedel-Crafts-Type Reactions with Electrochemically Generated Electrophiles from Donor-Acceptor Cyclopropanes and -Butanes. And the article contained the following:
A general electrochem. method to functionalize donor-acceptor (D-A) cyclopropanes and -butanes with arenes utilizing Friedel-Crafts-type reactivity is discussed. The catalyst-free strategy relies on the direct anodic oxidation of the strained carbocycles, which leads after C(sp3)-C(sp3) cleavage to radical cations that act as electrophiles for the arylation reaction. Broad reaction scopes in regard to cyclopropanes, cyclobutanes, and aromatic reaction partners are presented. Addnl., a plausible electrolysis mechanism is proposed. The experimental process involved the reaction of 1,4-Dimethoxybenzene(cas: 150-78-7).Formula: C8H10O2
The Article related to cyclopropane cyclobutane arene electrochem friedel crafts type reaction, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: General and other aspects.Formula: C8H10O2
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