Wang, Haiying; Yang, Weiwei; Baldridge, Kim K.; Zhan, Cai-Hong; Thikekar, Tushar Ulhas; Sue, Andrew C.-H. published an article in 2021, the title of the article was Spontaneous and induced chiral symmetry breaking of stereolabile pillar[5]arene derivatives upon crystallisation.Related Products of 150-78-7 And the article contains the following content:
Stereolabile pillar[5]arene (P[5]) derivatives, which are dynamic racemic mixtures in solution on account of their low inversion barriers, were employed as platforms to study chiral symmetry breaking during crystallization In the solid state, we showed that crystal enantiomeric excess of a conglomerate-forming P[5] derivative can be obtained by handpicking and Viedma ripening without the intervention of external chiral entities. On the other hand, in the presence of Et D/L-lactate as both optically-active solvents and chiral guests, the handedness of P[5] derivative crystals, either forming racemic compounds or conglomerates upon condensation, can be directed and subsequently inverted in a highly controllable manner. The experimental process involved the reaction of 1,4-Dimethoxybenzene(cas: 150-78-7).Related Products of 150-78-7
The Article related to pillararene preparation cd crystal structure inclusion reaction, Physical Organic Chemistry: Other Reactions, Processes, and Spectra and other aspects.Related Products of 150-78-7
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem