Martinez, Antonio Rosales; Enriquez, Lourdes; Jaraiz, Martin; Morales, Laura Pozo; Rodriguez-Garcia, Ignacio; Ojeda, Emilio Diaz published an article in 2020, the title of the article was A concise route for the synthesis of tetracyclic meroterpenoids: (±)-aureol preparation and mechanistic interpretation.SDS of cas: 150-78-7 And the article contains the following content:
A new concise general methodol. for the synthesis of different tetracyclic meroterpenoids was reported, (±)-aureol was the key intermediate for the general route. The synthesis of (±)-aureol were achieved in seven steps (28% overall yield) from (±)-albicanol. The key steps of this reported route included a C-C bond-forming reaction between (±)-albicanal and a lithiated arene unit and a rearrangement involving 1,2-hydride and 1,2-Me shifts promoted by BF3•Et2O as an activator and water as initiator. The experimental process involved the reaction of 1,4-Dimethoxybenzene(cas: 150-78-7).SDS of cas: 150-78-7
The Article related to aureol preparation, aureol, natural products synthesis, tetracyclic meroterpenoids, Terpenes and Terpenoids: General and other aspects.SDS of cas: 150-78-7
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem