Synthesis of 2-Aryloxy-1,3-dienes from Phenols and Propargyl Carbonates was written by Ishida, Naoki;Hori, Yusaku;Okumura, Shintaro;Murakami, Masahiro. And the article was included in Journal of the American Chemical Society in 2019.Formula: C13H12O2 The following contents are mentioned in the article:
A convenient method for the synthesis of 1,3-dienes from readily available compounds is reported. 2-Aryloxy-1,3-dienes are produced stereoselectively by a nickel-catalyzed reaction of propargyl carbonates with phenols. Functional group tolerance is broad to allow iodo, formyl, and boryl groups. The resulting 1,3-dienes are of much synthetic value because they can participate in a wide variety of reactions, including the Diels-Alder reaction. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Formula: C13H12O2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Formula: C13H12O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem