Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes was written by Wang, Jingyang;Wang, Yu;Ding, Guangni;Wu, Xiaoyu;Yang, Liqun;Fan, Sijie;Zhang, Zhaoguo;Xie, Xiaomin. And the article was included in Tetrahedron Letters in 2021.COA of Formula: C13H12O2 The following contents are mentioned in the article:
An efficient and mild catalytic deallylation method of aryl allyl ethers was developed, with com. available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process was compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2COA of Formula: C13H12O2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.COA of Formula: C13H12O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem