Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes was written by Wang, Jingyang;Wang, Yu;Ding, Guangni;Wu, Xiaoyu;Yang, Liqun;Fan, Sijie;Zhang, Zhaoguo;Xie, Xiaomin. And the article was included in Tetrahedron Letters in 2021.Electric Literature of C13H12O2 The following contents are mentioned in the article:
An efficient and mild catalytic deallylation method of aryl allyl ethers was developed, with com. available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process was compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Electric Literature of C13H12O2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Electric Literature of C13H12O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem