Facile Hydrogenative Deprotection of N-Benzyl Groups Using a Mixed Catalyst of Palladium and Niobic Acid-on-Carbon was written by Yamamoto, Yuta;Shimizu, Eisho;Ban, Kazuho;Wada, Yoshiyuki;Mizusaki, Tomoteru;Yoshimura, Masatoshi;Takagi, Yukio;Sawama, Yoshinari;Sajiki, Hironao. And the article was included in ACS Omega in 2020.Product Details of 103-16-2 The following contents are mentioned in the article:
Nb2O5/C was prepared from activated carbon, H2O, and NbCl5; in the presence of a combination of Nb2O5/C and Pd/C, benzylamines, benzyl carbamates, and benzyl ethers underwent hydrogenolysis in MeOH to yield amines and alcs. The combination of Nb2O5/C and Pd/C was used five times for the debenzylation of N-benzyldioctylamine to give product in 82->97% yield with a decrease in yield in the fourth reaction. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Product Details of 103-16-2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Product Details of 103-16-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem