Cakar, Ayse Erdogan et al. published their research in Journal of Molecular Structure in 2022 | CAS: 103-16-2

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Synthetic Route of C13H12O2

Determination of the surface thermodynamic characteristics and the structural isomer separation ability of new synthesized phenylbenzoate-based three-ring calamitic liquid crystals by inverse gas chromatography was written by Cakar, Ayse Erdogan;Cakar, Fatih;Ocak, Hale;Karavelioglu, Selvi;Eran, Belkiz Bilgin;Cankurtaran, Ozlem. And the article was included in Journal of Molecular Structure in 2022.Synthetic Route of C13H12O2 The following contents are mentioned in the article:

Two different new calamitic liquid crystals (LCs), 4-[4-(((S)-3,7-dimethyloctyloxy)phenoxy)carbonyl]phenyl 4-(n-decyloxy)benzoate (DPDEB) and 4-[4-(((S)-3,7-dimethyloctyloxy)phenoxy)carbonyl]phenyl 4-(n-dodecyloxy)benzoate (DPDOB) were synthesized and characterized using 1H-NMR, and 13C-NMR. The LC behavior of the target compounds was investigated by optical polarization microscopy (PM) and differential scanning calorimetry (DSC). The selectivity coefficients, a, of the structural isomers at infinite dilution for the DPDEB and DPDOB LCs were determined for Bu acetate, Bu alc. and amyl alc. isomers. Surface energy anal. has been performed using inverse gas chromatog. (IGC). By using suitable solvents, the surface properties and separation power of isomers of DPDEB and DPDOB LCs were determined between 303.2 and 323.2 K. Experiments with LC’s have been conducted at infinite dilution to the specific adsorption enthalpy and the specific adsorption free energy. IGC measurements exhibited values of acidity constants (KA) of 0.033 and 0.057 and basic constants (KD) of 0.176 and 0.242 for DPDEB and DPDOB, resp. It has been found that all LCs show basic character. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Synthetic Route of C13H12O2).

4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Many esters have the potential for conformational isomerism, but they tend to adopt an s-cis (or Z) conformation rather than the s-trans (or E) alternative, due to a combination of hyperconjugation and dipole minimization effects. The preference for the Z conformation is influenced by the nature of the substituents and solvent, if present. Lactones with small rings are restricted to the s-trans (i.e. E) conformation due to their cyclic structure.Synthetic Route of C13H12O2

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem