Taglang, Celine published the artcileEnantiospecific C-H activation using ruthenium nanocatalysts, Formula: C4H12ClNO, the publication is Angewandte Chemie, International Edition (2015), 54(36), 10474-10477, database is CAplus and MEDLINE.
The activation of C-H bonds has revolutionized modern synthetic chem. However, no general strategy for enantiospecific C-H activation has been developed to date. We herein report an enantiospecific C-H activation reaction followed by deuterium incorporation at stereogenic centers. Mechanistic studies suggest that the selectivity for the α-position of the directing heteroatom results from a four-membered dimetallacycle as the key intermediate. This work paves the way to novel mol. chem. on nanoparticles.
Angewandte Chemie, International Edition published new progress about 1162054-86-5. 1162054-86-5 belongs to ethers-buliding-blocks, auxiliary class Aliphatic Chain, name is (S)-1-Methoxypropan-2-amine hydrochloride, and the molecular formula is C18H10F3NO3S2, Formula: C4H12ClNO.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem