Friedman, Adam A. published the artcileRh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza-Dihydrodibenzoxepines, Safety of 2-Methoxy-5-methylphenylboronic acid, the main research area is palladium rhodium ligand domino tandem reaction; chemoselectivity; domino catalysis; enantioselectivity; heterocycles; multi-catalytic reactions.
Under optimized reaction conditions, the synthesis of the target compounds was achieved using bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-hydroxydirhodium, palladium(II) acetate and bis(1,1-dimethylethyl)[2′,4′,6′-tris(1-methylethyl)[1,1′-biphenyl]-2-yl]phosphine as catalyst combination. Di-μ-chlorobis(η2-ethene)dirhodium was also used as a catalyst. Reactants included (ethenyl)pyridine derivatives, such as 3-chloro-2-ethenyl-5-(trifluoromethyl)pyridine, 5-chloro-6-ethenyl-3-pyridinecarbonitrile. Reactants inlcuded 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol derivatives The title compounds thus formed included benzoxepinopyridine derivative (I) and related substances [pyrido[3,2-b][1]benzoxepine derivatives]. Par.
Angewandte Chemie, International Edition published new progress about Alkenylation. 127972-00-3 belongs to class ethers-buliding-blocks, name is 2-Methoxy-5-methylphenylboronic acid, and the molecular formula is C8H11BO3, Safety of 2-Methoxy-5-methylphenylboronic acid.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem