Nikl, Joachim published the artcileDirect Metal- and Reagent-Free Sulfonylation of Phenols with Sodium Sulfinates by Electrosynthesis, COA of Formula: C11H16O2, the main research area is hydroxyarylsulfone preparation electrochem green chem; phenol sodium benzenesulfinate anodization cross coupling sulfonylation; C−H activation; cross-coupling; electrochemistry; oxidation; sustainable chemistry.
A novel electrochem. strategy for the synthesis of arylsulfones R1SO2R2 (R1 = 3-tert-butyl-2-hydroxy-5-methoxyphenyl, 2-hydroxy-5-methoxy-3-methylphenyl, 4-hydroxy-3,5-dimethoxyphenyl, 2-hydroxy-3-methoxy-5-methylphenyl; R2 = Me, Ph, 4-fluorophenyl, etc.) by direct sulfonylation of phenols with sodium sulfinates NaOS(O)R2 has been developed. The C,S-coupling products are of particular interest for chem. synthesis, material sciences and pharmaceutical sciences. By using this metal- and reagent-free electrochem. method, aryl and diaryl sulfones can be obtained directly in good yields. The established one-step protocol is easy to perform, scalable, and inherently safe, and enables a broad scope, which is not limited by quinoid-forming substrates.
Chemistry – A European Journal published new progress about Anodization. 121-00-6 belongs to class ethers-buliding-blocks, name is 4-Hydroxy-3-tert-butylanisole, and the molecular formula is C11H16O2, COA of Formula: C11H16O2.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem