Russell, D. H. published the artcileThe chemistry of C6H6O radical cations: a study of rearrangement reactions of halogen substituted ethyl phenyl ethers, Recommanded Product: (2-Chloroethoxy)benzene, the main research area is mass spectra phenoxyethyl halide; phenol ion mass spectra; cyclohexadienone ion mass spectra; rearrangement ethyl phenyl ether.
Exptl. data are reported on the rearrangement of phenoxyethyl halides to give [C6H6O]•+ (I) and the results compared with previous data. Determination of the metastable kinetic-energy release for mol. ions which decompose at low energy indicated that I formation occurs via competitive 1,2- and 1,3-H shifts from the alkyl C to O, followed by rate-determining C-O bond cleavage. For more highly activated mol. ions, rearrangement involves transfer of the alkyl H to the ortho position of the ring via a rate-determining 1,5-shift, followed by a 1,3-H shift from the o-methylene group to O and rapid C-O bond cleavage. More highly activated mol. ions produce I, which can undergo metastable decomposition to lose CO; kinetic-energy measurements for the latter reaction indicated that the majority of these I ions were also formed as PhOH ions.
Organic Mass Spectrometry published new progress about Mass spectra. 622-86-6 belongs to class ethers-buliding-blocks, name is (2-Chloroethoxy)benzene, and the molecular formula is C8H9ClO, Recommanded Product: (2-Chloroethoxy)benzene.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem